A typical calcination process involves the conversion of calcium carbonate to calcium oxide. (begin{array}{l}CaCo^{3}overset{Delta h}{rightarrow} CaO+ Coend{array} ) ... Calcination of bauxite and gypsum involving the removal of water of crystallisation in the form of water vapour.
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This breakthrough has broadened the available bauxite reserves and effectively mitigated the harmful effects of SiO 2 during the Bayer leaching process while minimizing bauxite residue emissions. Calciumsilica slag (CSS) emerges as a solid residue generated during the chemical predesilication of medium and lowgrade bauxite.
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The hydrometallurgy process of the "calcificationcarbonation method" (CCM; process flowchart shown in Fig. 1) was proposed (Zhang et al., 2017; Zhang et al., 2013; Lu et al., 2014; Lu et al., 2017) to convert the hydrated sodium aluminosilicate phase in Bayer red mud to CaO·SiO 2 and CaCO the calcification process, siliconcontaining phases (such as kaolinite in bauxite) are ...
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Bauxite residue, or red mud (RM), is an alkaline sludge waste produced via the alumina extraction process in bauxite mines. Depending on the source of bauxite, this residue can be considered as a ...
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The preparation process of highpurity PACl with calcium aluminum and bauxite is developed, and the production cost is lower than that of acid dissolving of aluminum hydroxide. The metal ions can be effectively removed from the liquid PACl solution at both room and high temperatures.
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Overall, the bauxitebased defluoridation process described here offers a method that is potentially (1) effective at remediating fluoride contaminated groundwater, (2) affordable to impoverished s, (3) easy to operate and maintain without skilled labor, (4) culturally appropriate, and (5) widely available in fluorideaffected regions w...
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The optimized process conditions were the bauxite/anthracite/slaked lime weight ratio of 100::, reduction temperature of 1450°C and reduction time of ... smelting process was used to recover iron and calcium aluminate slag from highferrous bauxite. The reduction reaction mechanism is expressed by the following equations
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He achieved this by using bauxite and lime as raw materials, and burning them together in a cupola furnace. Published by Rankin and Wright in 1915, the limealumina phase diagram demonstrates the presence of five calcium aluminate compounds—CA, CA 2, C 3 A, CA 6, and C1 2 A 7 .
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The solid addition of a calcium source, such as gypsum or bassanite avoids many of the complications mentioned thus far for 'inprocess' bauxite residue neutralisation, however it appears that the effectiveness of these compounds is compromised by encapsulation, requiring relatively higher dosages to be used.
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Bauxite is the principal ore of aluminum. The first step in producing aluminum is to crush the bauxite and purify it using the Bayer Process. In the Bayer Process, the bauxite is washed in a hot solution of sodium hydroxide, which leaches aluminum from the bauxite. The aluminum is precipitated out of solution in the form of aluminum hydroxide ...
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This process involves the separation of alumina from unwanted components such as iron, titanium, silica, calcium, vanadium, manganese, etc., in bauxite. In this process, bauxite is heated along with the caustic soda at high pressure (~30 atm), resulting in the formation of sodium aluminate (reactions (1)(4) ) ( Gil, 2005; Ma et al ., 2009 ).
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In general, a national acceptable synthesis method involves a twostep method where the bauxite, hydrochloric acid and calcium aluminate are used as raw materials to prepare liquid PAC [5,6]. And, in China, PAC is also based on those process to produce, however, which resulted in generation of large volumes of very acidic residue called ...
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Bauxite reaction residue (BRR) produced from the polyaluminum chloride (PAC) coagulant industry is a solid acidic waste that is harmful to environment. A low temperature synthesis route to convert the waste into water glass was reported. Silica dissolution process was systematically studied, including the thermodynamic analysis and the influence of calcium and aluminum on the leaching of ...
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The Pedersen process is a method to produce alumina from Alcontaining sources, and it is a more materialefficient method than the current commercial Bayer process, since the formation of bauxite ...
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[Show full abstract] process conditions were the bauxite/anthracite/slaked lime weight ratio of 100::, reduction temperature of 1450°C and reduction time of 20 min. Under these ...
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The added amount of calcium oxide has a large influence on the calcification dissolution process of bauxite, the mass fraction of Na 2 O in the calcified slag can be reduced to % when the ratio of calcium to silicon reaches :1, and the slag is a single hydrated garnet phase.
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This paper creates hydraulic binders using waste and a low energy input. Cements are produced with a bauxite refining residue (red mudRM), blended with limestone and lime, and fused at temperatures from 600 to 1200 °C. The Saudi RM investigated has significant Al and Si but low Ca. Therefore, lime (CaO) and limestone (CaCO3) are used, as a source of calcium, to harvest cementing hydrates ...
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In this process, bauxite is smelted and reduced, which yields pig iron and a calcium aluminate slag. Alumina is further produced from the slag through a hydrometallurgical process.
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The alkaline release kinetics and response relationship of NA with respect to the process of bauxite residue neutralization were explored in this study. ... and C 1s to higher values were also found in the NA treated bauxite residue. Moreover, the calcium in the bauxite residue could react with NA to form "bridges" between organic matter ...
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Bauxite residue, also known as red mud, is an abundant byproduct produced during the alumina production process from bauxite ore. As the demand for ecofriendly construction materials grows, researchers are exploring the potential of bauxite residue as a binding agent in cementitious composites. ... Thermally treated calcium carbide residue ...
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Data from alumina processing industry show an estimated global average production of bauxite residue (red mud) to be 1 to ton per ton of alumina, or about 150 million ton of red mud is produced annually. [ 1]
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Alternative sustainable process for bauxite treatment to alumina is the Pedersen process, which was patented in 1920s and was in operation in Norway for many years before closing down due to economic reasons. In this process, bauxite is smelted and reduced, which yields pig iron and a calcium aluminate slag. Alumina is further produced from the ...
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Sintered calcium aluminate is produced by sintering of high purity alumina and low silica limestone. Fused calcium aluminate is produced by melting of high grade bauxite and low silica limestone and then solidifying and crushing the molten material. In both the process of manufacturing selection of raw materials is an important aspect.
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The Pedersen process was commercialized and is a high temperature (molten state) process that can separate iron and calcium aluminate slag . The method is regarded to be more material efficient and flexible in terms of the raw materials qualification to produce alumina as it can holistically utilize the bauxite or other alumina sources and ...
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The sinter process is widely used to process the poorgrade diasporic bauxite ores with A/S below 7, in China and Russia, by sintering the bauxite ore with sodium carbonate and limestone to form sodium aluminate and calcium silicate. In the process, the sinter is then leached with water, caustic soda solution, and recycled liquor to dissolve ...
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Bauxite residue is a kind of strong alkaline waste produced in the production of alumina. Its longterm storage poses a potential threat to the environment. With the tightening of environment policies in various countries, the strong alkalinity of bauxite residue has become a bottleneck restricting .
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A process flow diagram of the Bayer process is shown in Exhibit 3. The primary purpose of a Bayer plant is to process bauxite to provide pure alumina for the production of aluminum. All bauxite refineries share five common process steps: (1) ore preparation; (2) bauxite digestion; (3) clarification; (4) aluminum hydroxide precipi tation; and (5)
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The Ca content in most bauxite ores was below the detection limit except in India bauxite, which contained % Ca. Fig. C shows the XRD patterns of the four bauxite ores. The main crystalline Al phase in all bauxites was gibbsite, and an additional crystalline Fe phase (hematite) was detected in Ghana, India, and Guinea bauxites.
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