Naphthalene Production from coal tar; The distillation and fractionation techniques are used in this process. Crude naphthalene is produced by cooling and crystallizing the middle portions, which contain the majority of the naphthalene. In order to produce refined naphthalene, the crude product is then placed into a distillation, washing, and ...
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Most naphthalene is derived from coal tar. From the 1960s until the 1990s, significant amounts of naphthalene were also produced from heavy petroleum fractions during petroleum refining, but presentday production is mainly from coal tar. Approximately tons are produced annually. Naphthalene is the most abundant single component of coal tar.
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High temperature coal tar (HTCT) is a coproduct of the coking process, whose objective is the production of metallurgical coke for use in the production of pig iron in blast furnaces. According to FernándezGarcía et al. (2017), HTCT is obtained with a yield of about 35 wt% in coking.
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naphthalene oil. NPCs. normalphase columns. OBSG. octyl bonded silica gel. OCAs. ... while the latter is a byproduct from coal coking process [1]. The output of coal tar accounts for 35% of coals in the furnace [2]. ... Li YC, Xin WL, Huang MG, et al. Industrial production technology of coal series needle coke. CN A, ...
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Naphthalene is an important component of high temperature coal tar and its content can reach more than 10%. Catalytic polycondensation of naphthalene is an effective way to prepare mesophase pitch and functional carbon materials. ... which may provide valuable hints for exploring the production process of mesophase naphthalene pitch. Declare of ...
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Coal tar is an important raw material for the production of valuable aromatic compounds [].It has more than 500 components, most of which are aromatic hydrocarbons, including benzene, toluene, xylene, anthracene, naphthalene, and phenanthrene [4, 5].These are precursors for the synthesis of products such as dyes, drugs, explosives, scents, preservatives, synthetic tars, paints, and pigments.
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Chemical Abstracts Service Registry Number: CAS (Coal tar creosote); CAS (Wood creosote). Synonyms: Coal tar oil; Brick oil; Heavy oil; Naphthalene oil; Liquid pitch; Wood creosote. Chemical/Pharmaceutical/Other Class: Phenolic Compound. Chemical Formula: A distillate of coal that contains an estimated 162 different compounds.. Estimated makeup is as follows: aliphatic ...
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A kind of method for preparing naphthalene at first is a Doak Tar Oil, and the boiling range of further purifying is 205～235 ℃ a coal tar distillate that obtains like this is commonly referred to naphtalene contain the such heterocycle component of naphthalene, methylnaphthalene, phenolic compound and benzothiophene, (G, people such as Gilbert, Ind, Eng, Chem, 53 ...
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To develop the in situ underground pyrolysis process of tarrich coal more scientifically, the effect of temperature and pressure on the distribution of pyrolysis products should be clarified. This paper selected the typical components in five distillates of light tar, phenol tar, naphthalene tar, washing tar, and anthracene tar as the main reaction products. 32 typical secondary reactions ...
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Naphthalene was first isolated from coal tar in 1819 by Alexander Garden; it represents about 10% of this complex mixture of aromatics. The industrial importance of naphthalene dates from the latter half of the last century, owing mainly to the ease with which it can be converted into sulfonic acids and thence also to the naphthols, for use as dyestuffs intermediates.
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The presentday process for fractionating coal tar primarily used in industry is continuous distillation. from the coal tar. When coal tar is received, it contains from 3% to 10% water. storage tank through a series of heat exchangers to increase the temperature from about 175OF to about 40OOF. The primary heat source . is . supplied by the
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To trace the behavior of naphthalene in the pyrolysis of coal tar, the pyrolysis of coal tar containing 14Clabeled naphthalene was carried out at 800−950 °C for 40−50 s. It was found that naphthalene has significant pyrolysis reactivity. The distributions of the radioactivities in compounds with 3−5 rings were,, and % at 800, 900, and 950 °C for 50 s, respectively ...
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Naphthalene is produced by the following processes: 1. Recovery from coal tar. 2. From petroleum Unidak process Hydeal process Process given by faith. 1. Recovery from coal tar: The tar acidfree chemical oil is charged to the system where most of the low. boiling components,, benzene, xylene, and toluene, are removed in the lightsolvent ...
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These advantages of the hydrorefining process have attracted the attention of numerous investigators. A laboratory study has been made of the effects of temperature, partial hydrogen pressure, and space velocity on the amounts of thionapthen and tetralin in the hydroraffinate made by the catalytic hydrorefining of coaltar naphthalene.
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Coal tar ( ) and coal tar pitch ( ) are the byproducts of the hightemperature treatment of coal to make coke or natural gas. These chemical products usually are thick, black or dark brown liquids or semisolids with a naphthalenelike odor. Coal tar also has a sharp, burning taste.
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The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic three ...
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Coal tar is a hazardous and toxic waste, a byproduct of coal gasification processes. Coal tar is a waste produced in industrial fields such as steel, power plant, and the cement industry. As a ...
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The Process Intensification for Syngas Hydrogen key technology area addresses control of chemical reactions in increasingly modular and intrinsically efficient reactors, allowing for streamlined processes with wellcoordinated unit operations, and with a focus on gasification of biomass and carbonaceous wastes into syngas, s.
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Crystallization has advantages for the production of highly purified products, such as operation at low temperatures compared to vaporliquid processes, ... Purification of naphthalene from naphthalenerich oil of coal tar distillates was explored by using the melt and solution crystallizations. The solidliquid equilibrium of naphthalene ...
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Naphthalene has a distinctive, strong odor, which is often described as sweet or tarlike. Its melting point is around 80°C (176°F), and it boils at around 218°C (424°F). Synthesis and Production. Naphthalene is predominantly produced from coal tar, a byproduct of the coal gasification process.
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