Red mud is a slimy caustic residue generated from alumina refining of bauxite ores. During the alumina extraction process, about 35 %40 % of the bauxite ores go into the residue as highly alkaline red mud slurry (pH ) which contains 15 %40 % of solid phase in volume [1, 2].Depending on the quality of bauxite ores, producing 1 t alumina basically generates t red mud [].
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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3 ), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
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The specific process included pressure leaching by hydrochloric acidextraction separation of leaching solutiondirect pyrolysis of aluminum chloride solution to produce alumina. As shown in Fig. 1, first, the highiron bauxite was treated by acid leaching, and the solution containing aluminum chloride and ferric chloride was obtained.
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In the hydrothermal process, Na2CaSiO4 in the aluminaleaching residue is converted into NaOH and Ca5Si6O16(OH)2·4H2O in the alkali solution, and the residual alumina is converted into Ca3Al2SiO8 ...
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Red mud, also referred to as bauxite residue, is the largest process waste produced during alumina production from bauxite ore by the Bayer method. Approximately 12 tons of red mud are produced for every ton of alumina produced 1. Global red mud manufacturing is anticipated to be 200 million tons annually.
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Leaching of Alumina from Bauxite ore | Bayer process | Class 12 Chemistry | MetallurgyAfter watching this video, you will be able to* Explain the steps invol...
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More than 90% of the world's commercial manufacture of alumina is obtained by hydrochemical sodium hydroxide extraction of bauxite through the conventional Bayer process.
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Keywords Scandium ·Rare earth elements ·Bauxite ·Bayer process Introduction The Bayer process is the main process applied to obtain alumina from bauxite ore. The mineral is dissolved using sodium hydroxide in digesters, which obtain sodium aluminate in solution and a solid phase called red mud; the two are separated by the clarification ...
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where x = 1 for monohydrate hard alumina bauxite or monohydrate soft alumina bauxite; x = 3 for the trihydrate alumina bauxite. Among them, trihydrate alumina bauxite is the easiest to leach, with a typical leaching temperature of 140~145 °C and Na 2 O mass concentration of 120~140 g/L. Monohydrate soft alumina bauxite is more difficult to ...
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1. Introduction. Red mud (RM) is a waste generated during bauxite processing for alumina production. The most common method for bauxite processing is the Bayer process, where raw material is digested under high pressure by NaOH to obtain a pregnant sodium aluminate solution [].During highpressure leaching, nonsoluble elements such as iron, titanium, and refractory or precipitated during ...
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Introduction. Alumina (Al 2 O 3) is a material which has been studied extensively due to its wideranging applications in areas such as adsorbents and is traditionally obtained from the Bayer Process, which recovers aluminium from bauxite via a caustic digestion process, followed by crystallisation of aluminium hydroxides from the sodium aluminate mother liquor (Power et al ...
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Lowgrade bauxite ores are not favorable in the conventional Bayer process for alumina production, as they are producing more bauxite residue (red mud) and accompanying lower alumina yield than highgrade ores. In the current study, the thermodynamics and characterization of calciumaluminate slags and pig iron produced from smelting reduction of high iron and silicacontaining bauxites are ...
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The Bayer process produces alumina from the bauxite ore, and the HallHéroult process leads to the dissolution of the alumina powder into cryolite batch to produce the metal aluminum. ... (OH) 3 obtained in the Bayer process is easier than do for aluminum salt like aluminum chloride (AlCl 3), obtained by acid leaching of nonbauxites ...
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Abstract In view of the shortcomings of traditional comprehensive utilization of high iron bauxite resources to produce alumina, such as high energy consumption and long process flow, this paper proposed a doublecycle process for alumina production. As a main component in highiron bauxite, iron(Fe) has adverse effect on the recovery of aluminum. Removal of iron is essential for recovery of ...
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Bauxite mine tailings can be used as the reserve resources of aluminium and lithium. In this study, a less energy consumption treatment method for extracting aluminium and lithium from bauxite mine tailings has been proposed, which used mixed acid to leach aluminium and lithium from tailings directly, avoided roasting for reducing energy consumption, and obtained effective minerals ...
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This paper describes a novel process, hematite involved roasting − alkaline leaching − Bayer digestion, to extract silica and alumina from highalumina coal gangue (HACG). The phase transformations during roasting were investigated through Xray diffraction, Xray photoelectron spectroscopy, scanning electronic microscope, and energydispersive spectrometer. The silica and alumina ...
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The results obtained showed that 99% of Al 2O 3 was leached out using 200+270 mesh ore particle size at a reaction temperature of 105 °C for 60 min reaction time with 250 g/L NaOH. The solidtoliquid ratio was maintained constant at 1:20. The results indicated that leaching of bauxite is the rate controlling process.
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Red mud, also referred to as bauxite residue, is the largest process waste produced during alumina production from bauxite ore by the Bayer method. Approximately 12 tons of red mud are produced ...
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As an alkaline leaching method, roastingleaching process is a potential way to separate silica and alumina in primary alumina/silicabearing minerals (Herbert and Hans, 1960, Luo et al., 2016, Qiu et al., 2004, Rayzman et al., 2003, Smith, 2009).After roasting at >980 °C, the silica from the decomposition of kaolinite can be selectively extracted atmospherically by alkaline solution, and ...
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Highsilica bauxite is not used to obtain sandygrade alumina owing to its low alumina/silica ratio (μ Si < 3). Acidic methods, such as the use of HCl and NH 4 HSO 4, show promise for treating this raw leaching of boehmitekaolinite bauxite from the Severoonezhsk deposit mine (Arkhangelsk region, Russia) using a mixture of NH 4 HSO 4 and H 2 SO 4 was investigated for the first time.
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A closedloop valorization process, combining carbothermic smelting and acid baking water leaching was developed to recover scandium, aluminum, and iron from bauxite residue, a major side product of aluminum production. This process employs carbothermic smelting to recover 99% of the iron in the starting residue as crude metallic iron, which can be separated from slag that contains ...
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The purity of aluminum oxide obtained from this process is about 97% and its recovery percentage is about 98%. ... the optimal parameters for bauxite tailings leaching, producing a g/L Al and ...
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Concentration of Rare Earth Elements (Sc, Y, La, Ce, Nd, Sm) in Bauxite Residue (Red Mud) Obtained by Water and Alkali Leaching of Bauxite Sintering Dust May 2020 Minerals 10(6):500
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